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Doctor Who--Truly, you are a man after my own heart. However, for the "classic" series, I would personally only go with the credits from the Tom Baker era onwards. Even through Jon Pertwee the effects weren't quite up to the task. I would also nominate the "new" Who opening credits as well.
No "Twilight Zone"? Rod Serling's opening monologue is iconic. Oft-parodied, never equaled. And I would also nominate "The Addams Family."
And, frankly, "Friends." Catchy song, good sequence.